liquid-liquid EC

14 posts

Electrochemistry of selected quinones at immiscible n-octyl-2-pyrrolidone/aqueous interface using a three-phase electrode system

Vishwanath’s research on cation transfer at a three-phase junction was just published1 in Electrochimica Acta. This paper looks at transfer of cations driven by a redox reaction in an organic droplet immobilised on the electrode surface. The droplet is small enough not to cover the whole electrode area, so a […]

Paper-based system for ion transfer across the liquid-liquid interface

In a paper just accepted for publication in Analytical Chemistry Marta, Emilia, and Martin, together with Damien Arrigan from Curtin University, and our former intern Alexandra Pacowska, show how ion-transfer across the liquid-liquid interface can be studied in a paper-based system. One of the problems when studying ion-transfer between an organic […]

SECM study of hydrogen photogeneration in a 1,2-dichloroethane | water biphasic system with decamethylruthenocene electron donor regeneration

Wojtek had another publication in the series of papers on ion-transfer for H2 and H2O2 generation at liquid|liquid interfaces. In this paper, we continue our studies on hydrogen evolution reaction (HER) at the Interface between Two Immiscible Electrolyte Solutions (ITIES). This time, we have generated hydrogen by using photoelectroactive redox […]

H2O2 Generation at a Carbon-Paste Electrode with Decamethylferrocene in 2-Nitrophenyloctyl Ether as a Binder: Catalytic Effect of MoS2 Particles

Another paper in the series on H2O2 generation at liquid|liquid interfaces appeared in ChemElectroChem a while back. Wojtek is a co-author together with members of the Opallo-group and Hubert Girault from Lausanne. In the paper we describe the use of a carbon paste electrode (CPE) for generation of H2O2 at […]