liquid-liquid EC

14 posts

Three-phase electrochemistry of a highly lipophilic neutral Ru-complex having tridentate bis(benzimidazolate)pyridine ligands

After a long haul, our paper describing three-phase experiments with a new hydrophobic Ru-complex redox-probe was finally published in Electrochimica Acta. This work is a collaboration between our group and Prof. Masa-Aki Haga’s at Chuo University in Tokyo. About two years ago Haga visited our institute and gave a talk, […]

Electrochemical reduction of 7,7,8,8-tetracyanoquinodimethane at the n-octyl pyrrolidone/water/electrode three-phase junction

Continuing our investigations of the behaviour of various redox probes at three-phase electrodes we have just published a paper looking at TCNQ (7,7,8,8-tetracyanoquinodimethane) in a standard droplet-based setup. The reason we choose TCNQ is that it’s a quinone related to the ones we studied in our previous publication on transfer […]

Facilitated cation transfer at a three-phase junction and its applicability for ionophore evaluation

We’re on a roll. Another cation transfer paper was accepted1, also in Electrochimica Acta. This is work done by Marta and our undergrad student Julia. They were investigating transfer of cations at the three-phase junction driven by reduction of the fullerene C60 and facilitated by the addition of ionophores to […]